Mineralomimetic sodalite- and muscovite-type coordination frameworks. Dynamic crystal-to-crystal interconversion processes sensitive to ion pair recognition.
نویسندگان
چکیده
A flexible sodalite-type metal organic framework [Cu(pyrimidine-2-olate)2]n (1R) is obtained in a self-assembly process involving Cu2+ ions and pyrimidine-2-olate ligands. 1R suffers a series of sequential and reversible structural changes upon solid-liquid sorption processes of metal nitrates. The 1C-to-1O transformation occurs only with large cations.
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ورودعنوان ژورنال:
- Journal of the American Chemical Society
دوره 126 10 شماره
صفحات -
تاریخ انتشار 2004